ENGLISH |
中国科研实验室
| 发表年度： | 2016 |
|---|---|
| 期： | 24 |
| 卷： | 9 |
| 页： | 3465-3472 |
| 摘要： | In light of the increasing concern about the energy and environmental problems caused by the combustion of petroleum-based fuels (e.g., jet and diesel fuels), the development of new procedures for their sustainable production from renewable biomass-derived platform compounds has attracted tremendous attention recently. Long-chain ketones/alcohols are promising fuel components owing to the fuel properties that closely resemble those of traditional fuels. The focus of this report is the production of long-chain ketones/alcohols by direct upgrading of biomass-derived short-chain alcohol mixtures (e.g., isopropanol-butanol-ethanol mixtures) in pure water. An efficient Pd catalyst system was developed for these highly selective transformations. Long-chain ketones/alcohols (C-8-C-19), which can be used as precursors for renewable jet/diesel fuel, were obtained in good-to-high selectivity (>90%) by using the developed Pd catalyst. |
| 刊物名称： | CHEMSUSCHEM |
| 影响因子： | 7.804 |
